Forest FermiGoldenRule Notes

Fermi's Golden rule is used to calculate the probability (per unit time) of a quantum mechanical transition between two quantum states. Although Fermi first coined the term "Golden Rule", Dirac developed most of the machinery.

The first part of the Golden rule is the transition matrix element [math]M_{i,f}[/math]

[math]| M_{i,f}| ^2 = \int \psi_i^{*}(\vec{r}) H_{int} \psi_f(\vec{r}) dr^3[/math]

where

[math]\psi_i[/math] = initial quantum state of the system which is an eigenstate of the time independent ("steady state") Hamiltonian ([math]H_0[/math])

[math]\psi_f[/math] = final quantum state of system after a transition

[math]H_{int}[/math] = the part of the total Hamiltonian ([math]H_{tot}[/math]) which describes the interaction responsible for the transition.

[math]H_0[/math] = Unperturbed ("steady state") Hamiltonian

[math]H_{tot} = H_0 + H_{int}[/math] = total Hamiltonian describing the quantum mechanical system

[math]dr^2[/math] integration over all space