Insulators under a high voltage
Introduction
Air is one of insulators that prevent charge exchange between two charged conductors. Parallel plates is an example where the air is insulating the negatively charged plate from he positively charged one. Nevertheless, air does keep this properties when the voltage difference between the plates causes air ionization. the process will produce free electrons accelerates toward the positive plate.Enough number of these electrons will make the air a conductor and sparking is observed on the plates.
References
Dr JP Holtzhausen, Dr WL VoslooHigh "Voltage Engineering Practice and Theory" (online drift copy)