Electric QuadrupoleMoment Forest NuclPhys I
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Electric Quadrupole Moment of a Nucleus
Pages 104-111
As in the dipole calculation we assume that the object is in a state such that its maximum total angular momentum is along the z-axis.
or
then
From definition of quadrupole moment for a single charged object/particle.
The origin of this comes from electron-statics.
You expand the electric potential in terms of spherical harmonics.
because
\vec{E} = -\vec{\nabla} \Psi (r)