Fission Fragment Diffusion Through TRISO

File:DE-FOA-001515.pdf

Text from Appendix A

RADIOISOTOPE RETENTION IN GRAPHITE AND GRAPHITIC MATERIALS (RC-2) (FEDERAL POC – MADELINE FELTUS & TECHNICAL POC – PAUL DEMKOWICZ) (ELIGIBLE TO LEAD: UNIVERSITIES ONLY) (UP TO 3 YEARS AND $800,000)

Graphite is a primary core material across multiple types of advanced reactors (i.e., HTGR, FHR, and MSR) which have common material issues such as irradiation-induced material property changes, chemical reactivity, and material degradation. Fundamental studies determining the underlying mechanisms driving the material behavior as well as the impact from these effects on the core behavior is required for design and licensing can be completed for these advanced reactor concepts. A major issue of concern for MSR, FHR, and VHTR designs is the retention of activated fission products within graphite and graphitic materials such as the graphitic matrix composite used in TRISO particle fuel forms (pebbles or compacts). Radioactive material of fission product release from the fuel or from neutron reactions with molten coolant and fuel (lithium in FLiBe or FLiNaK in MSR designs) can be retained in carbon matrix, carbon-carbon composites, and graphite components. Research is needed on those graphite properties that are important for retention (and potential release) of these radioisotopes from a material possessing a graphitic crystal structure. Of particular interest is the chemisorption potential for various species, RSA efficiency, diffusion and intercalation efficiency, microstructure effects (grain size, BET, porosity distribution, source material), and at partial pressures of hydrogen (tritium and entrained water) over a range of high temperatures (500-1600C). This will assist in determining total inventory of retained products for accurate source term calculations required for licensing, determining the possibilities of tritium removal from carbon-based materials, and core component performance issues. The sorption/desorption isotherms of key fission products (including silver, cesium, strontium, and europium) in irradiated nuclear grade graphites for the high temperature reactors need to be determined. Research projects may use un-irradiated graphitic material and non-radioactive isotopes of the key fission products as surrogates to determine fission product retention behavior; however, comparison of parameters with the results from irradiated TRISO fuel forms and irradiated graphite experiments is encouraged. The objective of this project is to assess the retention of activated fission products within graphite as a function of the microstructural, fission product, and environmental conditions examined. Overall project results should include a description of all experimental conditions examined, analytical methods employed, and resulting effects on transport and retention of the various species examined.

Irradiate and perform PAA on graphite films

Fission Fragments of Interest That are measurable with PAA

strontium

The Reaction

[math]{88 \atop 38} Sr_{50} + \gamma \rightarrow {87 \atop 38} Sr^*_{49} + {1 \atop 0} n[/math] , 2.8 hr , 388.5 keV

lesser abundant natural isotopes

[math]{86 \atop 38} Sr_{48} + \gamma \rightarrow {85 \atop 38} Sr^*_{47} + {1 \atop 0} n[/math], 67 minute, 232 keV

[math]{87 \atop 38} Sr_{49} + \gamma \rightarrow {86 \atop 38} Sr^*_{48} + {1 \atop 0} n[/math]

[math]{84 \atop 38} Sr_{46} + \gamma \rightarrow {83 \atop 38} Sr^*_{45} + {1 \atop 0} n[/math]

Proton knockout makes nuclear waste beta emitter (Rb) that decays to Se-87

[math]{88 \atop 38} Sr_{50} + \gamma \rightarrow {87 \atop 37} Rb_{50} + {1 \atop 1} p \rightarrow {87 \atop 38} Sr^*_{49} + {0 \atop -1} \beta [/math]

silver

The Reaction

[math]{107 \atop 47} Ag_{60} + \gamma \rightarrow {106 \atop 47} Ag^*_{59} + {1 \atop 0} n[/math], 8.3 day, 451 keV

[math]{109 \atop 47} Ag_{62} + \gamma \rightarrow {108 \atop 47} Ag^*_{61} + {1 \atop 0} n[/math], 23 minute half life, 511 keV is dominant gamma line

cesium

The Reaction

[math]{133 \atop 55} Cs_{78} + \gamma \rightarrow {132 \atop 55} Cs^*_{77} + {1 \atop 0} n\gamma \rightarrow {132 \atop 54} Xe^*_{76} + {0 \atop -1} \beta[/math], 6 days, 667 keV

europium

The Reaction

[math]{151 \atop 63} Eu_{88} + \gamma \rightarrow {150 \atop 63} Eu^*_{87} + {1 \atop 0} n[/math], 37 yrs, 334, 439 , 584 keV

[math]{151 \atop 63} Eu_{88} + \gamma \rightarrow {150 \atop 63} Eu^*_{87} + {1 \atop 0} n \rightarrow {150 \atop 62} Sm^*_{88} + {0 \atop 1} \beta^+ [/math], 13 hrs, 334, 406 keV

[math]{153 \atop 63} Eu_{90} + \gamma \rightarrow {152 \atop 63} Eu^*_{89} + {1 \atop 0} n[/math], 96 min, 90 keV

References

File:Carter 2015 Thesis4DiffusionInGraphite.pdf

PAA_Research

Ag Diffusion

File:Gerczak JNM 2015.pdf

File:VanRooyen HTR2014prodceedings.pdf

IAC_Experiments